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The crystal structure of Ce16Ru8In37

Identifieur interne : 000225 ( Russie/Analysis ); précédent : 000224; suivant : 000226

The crystal structure of Ce16Ru8In37

Auteurs : RBID : Pascal:07-0368597

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Abstract

The ternary intermetallic Ce16Ru8In37 was synthesized by arc-melting from elemental Ce, Ru, and In under an argon atmosphere. The crystal structure of Ce16Ru8In37 was determined from the single-crystal X-ray diffraction data: a=4.7451(1) Å, b = 9.3518(2) Å, c= 32.6162(7) Å; space group Immm, Z= 1. The architecture of the crystal structure of Ce16Ru8In37 is based on CeIn3 units with cubic Cu3Au-type and can be presented as consisting of two different slabs: CeIn3 -like slab of composition Ce4In14.5 and a slab of composition Ce4Ru4In4.

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Pascal:07-0368597

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<title xml:lang="en" level="a">The crystal structure of Ce
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Ru
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In
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<front>
<div type="abstract" xml:lang="en">The ternary intermetallic Ce
<sub>16</sub>
Ru
<sub>8</sub>
In
<sub>37</sub>
was synthesized by arc-melting from elemental Ce, Ru, and In under an argon atmosphere. The crystal structure of Ce
<sub>16</sub>
Ru
<sub>8</sub>
In
<sub>37</sub>
was determined from the single-crystal X-ray diffraction data: a=4.7451(1) Å, b = 9.3518(2) Å, c= 32.6162(7) Å; space group Immm, Z= 1. The architecture of the crystal structure of Ce
<sub>16</sub>
Ru
<sub>8</sub>
In
<sub>37</sub>
is based on CeIn
<sub>3</sub>
units with cubic Cu
<sub>3</sub>
Au-type and can be presented as consisting of two different slabs: CeIn
<sub>3</sub>
-like slab of composition Ce
<sub>4</sub>
In
<sub>14.5</sub>
and a slab of composition Ce
<sub>4</sub>
Ru
<sub>4</sub>
In
<sub>4</sub>
.</div>
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<s0>The ternary intermetallic Ce
<sub>16</sub>
Ru
<sub>8</sub>
In
<sub>37</sub>
was synthesized by arc-melting from elemental Ce, Ru, and In under an argon atmosphere. The crystal structure of Ce
<sub>16</sub>
Ru
<sub>8</sub>
In
<sub>37</sub>
was determined from the single-crystal X-ray diffraction data: a=4.7451(1) Å, b = 9.3518(2) Å, c= 32.6162(7) Å; space group Immm, Z= 1. The architecture of the crystal structure of Ce
<sub>16</sub>
Ru
<sub>8</sub>
In
<sub>37</sub>
is based on CeIn
<sub>3</sub>
units with cubic Cu
<sub>3</sub>
Au-type and can be presented as consisting of two different slabs: CeIn
<sub>3</sub>
-like slab of composition Ce
<sub>4</sub>
In
<sub>14.5</sub>
and a slab of composition Ce
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Ru
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In
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